The conversion of COx into value-added inexperienced aromatics is taken into account as a promising path to achievethe world’s decarbonization attributable to its appreciable thermodynamic driving drive and atomic financial system the place low H/C ratio aromatics is chosen as product. It’s enabled by the bifunctional nano-catalysts composed of steel oxides with plentiful oxygen vacancies and acid zeolites, thus realizing the superior selectivity in hydrocarbons on the single go of COx conversion. On this mini-review, we primarily offered some thought-provoking insights at nanoscale of this difficult course of together with the proximity of lively websites, response mechanism, uneven desorption conduct of intermediates and remaining merchandise and total thermodynamical evaluation. The facile floor diffusion of intermediates owing to the proximity of lively websites stimulates the response, which follows an autocatalytic course of. This optimistic suggestions attributed to the autocatalytic cycle accelerates the transformation of vitality and supplies within the thermodynamically optimum path, making the response extremely selective in direction of the ultimate merchandise.This difficult coupling course of, like a nano-maze constituted by these micro-environment elements, is difficult by way of response pathway however extremely selective to a hard and fast path guided by total thermodynamics. Deep understanding of such a autocatalytic cycle on the nanoscale paves the way in which for the rational design of the next-generation high-performance catalysts.